Home > Nanocatalysis and Fossil Fuels Report
"Nanocatalysis and Fossil Fuels", contains an in-depth analysis of the impact of nanocatalysis on the global energy industry, a detailed description of the technologies involved, and profiles of the leading players.
Energy is the world's largest market, and one that has political
and strategic impacts unmatched by any other sector. Most countries
are entirely dependent for their energy needs on the finite resources
of fossil fuels. Fluctuations in energy prices can bring economies
to their knees, and allow otherwise less influential or developed
countries to become major players in world politics. While catalysis is as old as the chemical industry, recent advances
in nanocatalysis have started an inexorable shift in both the economic
and political balance of the fossil fuels market. As with other
technological shifts, control of the direction and magnitude of
the effects lies in the hands of the controllers and adopters of
the technology. It is notable in this respect that the most advanced
coal liquefaction catalytic technology is being applied in China
and has US government involvement. These technologies are still at the early stage, but interest from
the US Department of Energy and the Chinese government has already
allowed one small company to sign a $2 billion contract for the
commercialization of its nanocatalysis technology for coal liquefaction
in a remote region of China. Developments in nanocatalysis have the potential to • allow remote regions of the world to become self-sufficient in
oil, produced locally from coal reserves • allow stranded gas, which accounts for 80% of known gas reserves,
to be economically exploited • place a cap on oil prices, below the level desired by OPEC • help Russia to become a significant player in the global energy
market, emerging as a rival to OPEC • allow countries with large coal reserves such as the US and China
to become independent of imported oil should political or economic
factors favor this • cause the production of offshore oil to become increasingly marginal,
narrowing the difference between production costs and world prices,
and thus impacting the economies of major oil producers • help shift greenhouse gas emissions from vehicles to more centralized
locations, where they can be more effectively managed, and ultimately
pave the way to a hydrogen economy Nanocatalysis and Fossil Fuels
July 2002 • significantly reduce emissions of other pollutions such as nitrogen
oxides, sulfur dioxide (the cause of acid rain) and particulate
matter • promote waste recycling through conversion of plastic, rubber,
municipal waste and waste oil to clean fuel The distribution of world coal reserves is dramatically different
from world oil reserves, being concentrated in countries such as
China, the US, Russia, Australia and India. Economic extraction
of transportation fuel from coal could thus completely alter the
balance of power in terms of world energy supplies. Russia in particular,
especially with its close relationships with other countries in
the former Soviet Union, looks set to benefit from any shift in
power through its access to major coal and natural gas reserves.
This shift is just starting, with production of transportation
fuels, particularly ultraclean diesel, from coal now economically
viable for countries like China at prices in the OPEC target range
of $22 to $28 a barrel, thanks to nanotechnology. A few years hence
the technology will probably be viable also for the United States
and other coalrich, developed countries such as Australia. We are not about to see the bottom drop out of the oil market and
a resulting crash of economies in the Middle East, but their historical
power and their ability to affect the world economy through oil
prices, either deliberately or through wars and political turmoil,
seems destined to be significantly diminished for good. Nor are we about to see a major improvement in emissions of greenhouse
gases and other pollutants, but the new technologies do offer promise
of improvement and also a stepping stone to a future hydrogen economy,
with cities choked with car fumes becoming a thing of the past.
This will not happen tomorrow but advances in fuel cell technology,
through nanocatalysis and other nanotechnologies, show great promise
of making this a reality some years down the road. Also influencing this dynamic is the potential of exploiting the
bulk of the world's gas reserves, which are currently uneconomic.
There is even a distant possibility of tapping a source of methane
(the main component of natural gas, and the cleanest of the fossil
fuels) that could last for thousands of years, in the form of methane
hydrates sitting at the bottom of our oceans. The same technologies will allow us to turn waste—oil, plastic,
rubber and domestic and factory waste—into clean fuels for our cars,
trucks and airplanes. Our dependence on fossil fuels does not look set to go away soon,
but the rules of the game will change, drastically limiting their
ability to throw economies and the world into turmoil and reducing,
given sufficient political will, the damage they do to the environment.
Nanocatalysis and fossil fuels........................................................................................7 Executive Summary ...................................................................................................7 Nanocatalysis .............................................................................................................9 Catalysts and nanotechnology................................................................................9 Introduction to catalysts.....................................................................................9 What does nanotechnology have to do with catalysis?....................................11 Nanoparticles ...............................................................................................12 Zeolites.........................................................................................................13 Aerogels and xerogels..................................................................................14 Biological support structures .......................................................................14 Early nanotechnology ..................................................................................15 Activity in nanocatalysis—some indicators.....................................................16 Some recent developments in nanocatalysis................................................21 Applications of catalysts to the energy markets ..................................................24 Fossil fuels .......................................................................................................24 Refining technology.....................................................................................24 Coal liquefaction technology .......................................................................24 Gas-to-liquid technology .............................................................................26 Waste-to-fuel technologies ..........................................................................27 Fuel cell technology.....................................................................................27 Energy Market Impact .............................................................................................29 Overview of the energy markets ..........................................................................29 Fossil fuels .......................................................................................................31 Oil ................................................................................................................31 Heavy / waste oil......................................................................................34 Coal ..............................................................................................................35 Reserves ...................................................................................................37 Coal gasification and integrated gasification combined cycle.................38 Integrated Gasification Combined Cycle (IGCC)........................................39 Coal liquefaction......................................................................................41 Gas ...............................................................................................................43 Stranded gas .............................................................................................47 Methane hydrates .....................................................................................49 Gas-to-liquid conversion..........................................................................49 Waste to fuel ................................................................................................50 Non-fossil-fuel energy sources ........................................................................50 Fuel cells ..........................................................................................................51 The hydrogen factor.........................................................................................52 Environmental impact..................................................................................................55 Global drivers for the development of nanocatalysts in the fossil
fuel sector .............62 Resource profiles .....................................................................................................62 Political framework..................................................................................................62 Reducing dependency on the import of oil ..........................................................63 The regulatory framework ...................................................................................63 At the starting gates: current primary energy consumption profiles........................65 Strategic map of possible consequences of nanocatalytic processes
on a global scale .................................................................................................................................66 Potential geopolitical consequences of reduced dependence on oil
........................67 Conclusions..................................................................................................................70 Units............................................................................................................................73 Further reading and resources......................................................................................74 Appendix 1 - Fossil fuel, nanotechnology, and catalysis patent
list...........................75
Despite earlier oil supply scares, most countries in the world are still heavily dependent on imported oil, especially for transport. Yet many of these countries have huge reserves of coal or gas that cannot currently be economically exploited.
Recent developments in the application of nanotechnology to catalysis are promising to lower oil price pressure through improved coal liquefaction and gas to liquid processes, allowing countries such as China, the US, Canada, India, Russia and Australia to significantly reduce or eliminate their requirements for imported oil.
This could cause a permanent downward adjustment in the price of oil that would render high-production-cost operations, especially those offshore, uneconomic, and significantly reduce the economic and political influence of oil-producing nations and OPEC.
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